Densification and sintering of ceramic nanocomposites for mid-IR solid state lasers

Reference Presenter Authors
(Institution)
Abstract
12-029 Victoria L. Blair Blair, V.L.(US Army Research Laboratory); Fry, A.(ORAU); Kilczewski, S.M.(Army Research Laboratory); Fleischman, Z.D.(Army Research Laboratory);

Transparent nanocomposites are a possible alternative to single-phase mid-IR solid state lasers, as nanocomposites could potentially avoid the materials performance tradeoffs. We aim to use a ceramic nanocomposite containing Er:Y2O3 and MgO to combat two challenges for mid-IR laser materials: dissipation of heat generated in lasing and luminescence quenching by multi-phonon relaxation. However, having two materials with different indices of refraction is a new challenge to the production of transparent parts.  Increasing the amount of Er:Y2O3 leads to changes in the sintering processes to obtain dense parts while maintaining the desired microstructure. As more Er:Y2O3 is introduced to the system, the MgO grain size decreases.  However, this leads to larger Er:Y2O3 grains that cause increased light scattering. We will show how initial crystallite size, sintering temperatures and pressures affect the final microstructure and mid-IR transmission.

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